![]() Of course, these data can be of experimental origin, however, it can also be an indication for faked values (especially in the case of a large number of perfectly fitting analyses). About 5–10% of the publications show elemental analysis data where most or all values deviate ≤0.10% from the theoretical calculation. We checked the deviation of theoretical and experimental elemental analysis values in several issues of bioinorganic and general chemistry journals. ![]() Based on our experience as reviewers in various peer-reviewed journals, there are more and more manuscripts/publications, where the presented values are so perfect that it is extremely hard to believe that real values were actually measured. However, this is where the problems begin. This is essential for all subsequent biological, catalytical and analytical studies, which rely on this information for their accuracy. of Organometallics, 2 Angewandte Chemie, 3 Chemistry – A European Journal 4). Usually, the measured values have to fit the gold standard of ± 0.40% of the calculated values to guarantee sufficient purity (see author guidelines e.g. Also, in case of multidisciplinary journals like Angewandte Chemie, Journal of American Chemical Society, Chemical Science, Chemistry – A European Journal, etc., this analysis is mandatory for synthetic (bio)inorganic chemistry. Inorganic Chemistry, Inorganic Chemistry Frontiers, Organometallics, Dalton Transactions, Journal of Inorganic Biochemistry, Journal of Biological Inorganic Chemistry, and many more, elemental analyses of newly synthesized compounds are a requirement for publication. Thus, in peer-reviewed international (bio)inorganic chemistry journals e.g. A likely explanation is that characterization of the subclass of paramagnetic compounds by NMR spectroscopy is not meaningful. Reviewing elemental analysis data In contrast to synthetic organic chemistry, elemental analysis is an essential part of substance characterization in the field of (bio)inorganic coordination chemistry. rate constants (catalysis), biological data (medicinal chemistry) or material properties. As a consequence, this will generate wrong results when comparing e.g. Inorganic salts like NaCl derived from insufficient purification protocols or co-crystallized water molecules cannot be detected by NMR spectroscopy or HPLC, which easily can lead to errors of about 10–20% in the molar mass. This is the feature that makes elemental analysis unique among characterisation tools. Nevertheless, these values allow conclusions about the elemental composition and as a consequence the purity of compounds. It delivers only a few values which show little compared to the large amount of information generated from e.g. Of course, elemental analysis seems to be a rather crude technique leading to nothing more than an empirical formula. 1 The typically analysed elements are carbon (C), hydrogen (H), nitrogen (N) and sulfur (S), rarely also oxygen (O) is measured.Īfter the invention of mass spectrometry, the introduction of high performance liquid chromatography (HPLC) and the rise of nuclear magnetic resonance (NMR), the importance of elemental analysis in synthetic organic chemistry declined (in contrast to (bio)inorganic chemistry). Fritz Pregl compiled the methods after adapting them to consume as little as a few milligrams of material for one analysis and founded Organic Elemental Microanalysis (OEM, or simplified: elemental analysis). The advancement of organic chemistry (identification of natural substances as well as synthetic approaches) was based on the information about the composition and the molar mass of chemical compounds. It has provided essential information about substances and their composition from the beginning of the development of chemical concepts and science in general. ![]() Introduction Elemental analysis marks the origin of chemical understanding. This would enable reviewers, editors and readers to better judge the presented results in the future. Within this article we discuss what realistic measured deviations from the theoretical composition of a compound are and present an approach to provide original elemental analysis data to support the listed values in the experimental sections. Our personal observation in the review process of numerous manuscripts over the last years revealed that the amount of questionable data is constantly increasing. ![]() with chromatograms, making this essential analysis prone to manipulations. However, in contrast to other analytical methods, there is no requirement to prove the presented values e.g. Elemental analysis provides a powerful analytical tool for purity determination of compounds and is a prerequisite for publication in many journals dealing with (bio)inorganic synthetic chemistry.
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![]() Hope this gives you a little peek into who I am. I think it would be really cool to get into designing symmetry in 3D art and have been seriously considering taking a Solid Works course to be able to begin designing in that venue. My hobbies include (but are not limited to) origami, spirograph art, and climbing. Follow these search tips to get the most out of the CPG. EPP 223 Course Description (PDF) EPP 701- Introduction to Common Plants for Wetland Delineation. Daniel Mackin Freeman and Dara ShifrerView all authors and affiliations. The Course Projections Guide is a tool to help students plan their academic careers by projecting which courses will be available. A trip around the country for 6 months in a VW Bus when I was 22 finally ended with me deciding to go back to school and I'm so very happy I did! Arts Course-taking and Math Achievement in US High Schools. However, I dropped out of college when I was 19 because I needed to grow up a bit before being ready for college. Meaning I grew up in Oregon City, graduated from Oregon City High School, and then went to the Art Institute of Portland (I told you I love art and math!) for computer animation. Well, that and I built a 17' tall trebuchet to launch pumpkins with :)īefore that, I was a student at Portland Community College where I found my passion for teaching mathematics when I started tutoring mathematics at the Cascade Campus back in 2007.īy now you may have guessed this, but I'm from here. I went to the University of Oregon where I got my BS in mathematics with a minor in physics - yup, I'm into physics as well! I think one of the coolest things I did there was create a circuit board that emulated the game Mastermind. Please send the following information to your academic adviser. If you have math or stat courses matched as LD or UD in your DARS report then we need to evaluate the courses. I did my master's project on the mathematics of origami, as one of my passions is bringing mathematics and art together to create beautiful things! Some transferred courses are matched automatically with PSU courses but many others are not, especially upper division courses. Working backwards, I graduated with my Masters degree in Mathematics from Portland State University in 2013, where I focused on Abstract Algebra and Dynamical Systems. I've also taught at all four campuses during that time but have made the SE campus my home for two years now. I've been a math instructor at PCC since 2012 and have taught classes from MTH 20 through MTH 261 - almost every course we offer here! - over that time-span. Hello! My name is Noah Dear, and I'm excited to be your instructor this term! Please feel free to address me as Noah throughout the term. This will be different for each graphic, as the customization options depend on the needs and capabilities of each particular graphic. Here you can change colors, text, and various opacities, and turn some aspects on or off. Now, once you select that graphic, you’ll notice some customization options in the Essential Graphics panel. Once you’ve installed your templates, drag your graphic of choice down to the timeline. Click on that button and install the template that you want.Īt this posting, there’s no way to install multiple templates simultaneously-you have to install one at a time. In the bottom right-hand corner of the Essential Graphics panel, you’ll see a little plus button in front of a square (pictured above). mogrt files (the template files that Premiere uses for the Essential Graphics panel) in Premiere, you need to open the Essential Graphics panel. Install these fonts before using these graphics-otherwise, they might not look correct. You’ll find all the fonts you need to use in title graphics in the download folder. With each of these templates, you’ll find specific tools that you can use to customize the animations, colors, and text to your liking.īefore using these templates, be sure you’re up to date with the most recent versions of Premiere and After Effects. The nice thing about using the Essential Graphics Panel to create templates like this is that it allows you to customize specific parameters and aspects of your motion graphics without going back and forth between After Effects and Premiere.Īs previously mentioned, the download includes the AE project file, so if you’d like to customize fonts, colors, and animation in a particular way that we didn’t have in the template, feel free to open the project up and change whatever you’d like. Download the 21 Motion Graphics for Premiere Hereīy downloading, you agree not to resell or redistribute these free assets. ![]() In the download, you’ll find everything you need to get started. These motion graphics are free to use in any personal or commercial project. ![]() AE project file (customize however you’d like)ĭownload the 21 Free Motion Graphics for PremiereĬlick the button below to download the free pack of 21 Motion Graphics for Premiere.
![]() Despite shortcuts, PhpStorm offers convenient integration with GIT. This feature of the PhpStorm mostly gives us a hint of making our code more readable and more efficient because sometimes a developer may miss something and will need a suggestion on how to refactor the code. Before applying the changes, you can select a preview to evaluate which files will be changed. After doing so, the window opens, which gives us a rich choice of code refactoring. Refactoring the code has never been so easy as it’s by pressing Ctrl + Shift + Alt + T on the highlighted part of the code. as they’re generating the code that takes me a few minutes in a few seconds. I’m calling this combination, and the combination of Alt + Enter my J.A.R.V.I.S. We’ll see the popup window that prompts us to override a method, implement methods, add a constructor, getters and setters, and PHPDoc comments. It is handy, especially when we’re coming back the next day and trying to remember what we were working on the previous day. Also, in this window, we can start writing the name of the file of interest to us, and the IDE will filter the list. This shortcut is useful as it saves us time when looking up a class, a class method or property, or setting a property.Ĭtrl + E opens a popup window with files that we’ve recently opened. It’s just enough to write a piece of the desired text, and our magic tool will search for it for us and even group it into categories of fragments found in classes, files, symbols, and even menu items. adding interface methods that are required to implement.Īs we can see, this shortcut indeed makes our development process easier and faster, as we don’t need to write much by ourselves.īy double-clicking the Shift key, a pop-up window appears that allows us to search for any file, class, class method, property, or settings anywhere.updating the comment block by the method signature,.importing the class under the cursor into the use section,. ![]() Here is the list of actions offered by the shortcut: It displays a context menu with available actions depending on where the cursor is. We’ll take a look at the five most common shortcuts. ![]() One of the ways to achieve that is using shortcuts. PhpStorm takes care of the programer code efficiency and provides a convenient environment to make development faster. Despite PHP, this tool includes support for front-end technologies such as HTML 5, CSS, Sass, JS, TypeScript, etc. It supports all the features of the PHP language for modern and legacy projects. It’s a perfect development tool for all PHP developers, adapted for most popular PHP frameworks such as Laravel, Drupal, Symfony, etc. There are many of them, but one of the most popular and robust is PhpStorm. It’s an integrated development environment (IDE). Just like every artist, a programer needs a tool to create their masterpiece. Software development is an art in the IT world, and a software developer is an artist in that. Do you see? Using shortcuts saves us time and increases the possibilities of actions performed using the keyboard. When that combination of keys is done, for instance, if we want to copy the selected text faster, we can press Ctrl and C. ![]() A shortcut is a combination of a key or keys on the keyboard to execute a specific command that is intended to be done in several steps. Give it a try, and let us know how it goes on Twitter.In this article, we’ll talk about the benefits of using labels in our daily work. In the meantime, we hope WebStorm users enjoy the new and improved Astro developer experience. Yessss, please, inject astro support into my veins And other people seem pretty excited too: WebStorm is planning to add even more advanced features for Astro going forward. You can also install it directly from inside your WebStorm IDE by going to Preferences / Settings and searching for “Astro” in Plugins. To get started: Download the official Astro plugin from the JetBrains Marketplace. New features include syntax highlighting, code completion, automatic imports, refactorings, navigation, intentions, code folding, Emmet support, and auto formatting. With today’s update, WebStorm users get an improved development experience for Astro projects. WebStorm - a popular integrated development environment (IDE) for Javascript and related technologies by JetBrains - has just announced initial support for Astro. ![]() (2.44 meters) extendable height to maximum 20 ft. This ladder is available in sizes varying from a minimum 5 ft. Our range of Self Supporting Extension Ladder can be availed in several variants in terms of quality, sizes and steps. It is provided with additional function of extension and can be handled with relative ease. Being a heavy duty ladder it is highly durable, strong and long lasting in nature and hence, is widely used for small industrial purposes such as for maintenance of streetlights and for commercial use. 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There’s a lot of versatility there for kinda that slot that he’s in. “Very conscientious player, can play special teams, can be in the return game, can be a gunner. “His explosiveness, his speed, he can play inside and outside,” head coach Kliff Kingsbury said Wednesday. Luckily, Isabella’s ability to play multiple roles gave him a step up on his competition. While the wide receiver set career marks in 2020, it still wasn’t the production many expected to see from Isabella in Year 2. Last season, Isabella recorded 224 yards and two touchdowns on 21 catches (35 targets). He was waived on August 29, 2023, and re-signed to the practice squad. On July 28, 2023, Isabella signed with the Buffalo Bills. I was way behind, so it’s frustrating but I’m just doing what I can.” Andy Isabella (born November 18, 1996) is an American football wide receiver for the Buffalo Bills of the National Football League (NFL). “I gotta really fight my way to get put on the field now. “It sucks, the position I’m in,” Isabella said Wednesday. The Cardinals’ preseason came to an end and Isabella was left without any game tape. ![]() When he finally did make it out of COVID-19 protocols, another wrench was thrown into his plans in the form of Hurricane Ida.Īfter missing the first two preseason games, Isabella was poised for an extended look in the team’s finale against the New Orleans Saints.īut mid-flight, Arizona’s plane turned back around with the impeding hurricane approaching Louisiana. Arizona Cardinals place CB Malcolm Butler on retired list, make 15 cuts ![]() The NASM Optimum Performance Training Model, also called the OPT Model, is the creation and flagship of the successful NASM personal trainer certification program. The NASM Optimum Performance Training (OPT) Model sports performance training opt model They’ve also partnered with over ten thousand gyms and health and fitness clubs to provide location and employment opportunities for new and experienced trainers. The National Academy of Sports Medicine is one of the largest accredited certification companies for personal trainers, with over 1.3 million fitness professionals educated in over 100 countries with NASM trainers. They aim to set the fitness sector’s standard for health and wellbeing. The National Commission accredits NASM for Certifying Agencies, a nationally recognized third-party agency that ensures certification companies work at the highest standards. The National Academy of Sports Medicine is more than just a training company.įor over 30 years, NASM has been a global leader in personal training by helping personal trainers, coaches, and clients achieve their fitness goals, personally and through careers. The National Academy of Sports Medicine (NASM) Impact Now, let’s look at the 5 reasons getting your NASM certification for a personal training career is worth it. Why Should I Get A NASM Personal Trainer Certification? Certified Personal Trainers Can Make More Moneyīecause trainers with certification are often preferred when it comes to being hired by fitness facilities and the general public, this can often lead to better income opportunities due to increase opportunities to attract more clients.įitness professionals with a higher level of education and learning can demand a higher pay rate compared to those with lesser or no educational background. It helps gyms ensure that the hired fitness professional trainers have a good foundation of knowledge and are well prepared to help their clients and others train in the gym properly. Many gyms require certification for personal trainers that wish to work there. Potential clients interviewing fitness trainers to help with training and fitness often prefer to hire a CPT (Certified Personal Trainer). Why Should Personal Trainers Get Certified?Ĭertified trainers can be more knowledgeable and better trained than those without personal trainer certification and better positioned to help their clients achieve their goals. The additional NASM certification and the knowledge it provides are an advantage to personal trainers’ professional development, either as a hobby or a fitness career. This means assisting with advice regarding exercise, workouts, weight loss, food, nutrition, or general fitness and wellness tips.Ī certified personal trainer is a trainer who matches the above descriptions but has also taken a CPT course offered by a company such as NASM and has passed the final NASM certification exam. Personal Trainer VS Certified Personal TrainerĪ personal trainer is a person who helps clients achieve their overall health goals by sharing their knowledge and expertise. Final Thoughts on the NASM CPT Programs.Phase 3 – Muscular Development/Hypertrophy.The Extra Bonus of Continuing Education.NASM Offers Other Certification and Specialization Courses 100% Online Courses For Personal Trainers The NASM Optimum Performance Training (OPT) Model ![]() Why Should I Get A NASM Personal Trainer Certification?.Certified Personal Trainers Can Make More Money.Why Should Personal Trainers Get Certified?.Personal Trainer VS Certified Personal Trainer.8 weeks of in-person lectures and practices on Mondays & Wednesdays by Purdue Fitness Professionals.AFAA’s Group X certification is accredited by the National Commission for Certifying Agencies (NCCA), and was the first to release nationally standardized guidelines for fitness professionals. This course is designed to equip you with the knowledge and skill set necessary to effectively lead, design, and execute a group exercise class as an AFAA Certified Group X Instructor. Please note: All materials will be distributed on the first day of class.īecome a Certified AFAA Group Fitness Instructor Opportunity to take CPR class at Recreation & Wellness.In-person and virtual lab opportunities.8 Weeks of in-person/virtually streamed instruction on Tuesdays by Purdue Fitness Professionals.The NASM-CPT certification is proudly accredited by the National Commission for Certifying Agencies and provides aspiring fitness professionals with the most up-to-date science and content about exercise technique, instruction, and program design. This course is designed to equip you with the knowledge and skillset necessary to effectively lead, design, and execute a personal training session as a NASM Certified Personal Trainer. ![]() By contrast, he added, Domino's new gourmet pizzas priced as high as $14 had seen a sales jump in some affluent areas. When Khetarpal visited Domino's stores in Chennai and other cities, he said he saw customers emptying out their pockets and only being able to scrape together 49 rupees. Many low and middle-income earners who saw dining at foreign chains as a lifestyle upgrade when the economy boomed are tightening belts as inflation bites, while the wealthier continue to spend on products like pricier smartphones, and SUV cars whose sales are touching new highs. The industry players described a tale of two consumers in a country with yawning gaps between rich and poor. There have been more shocks in recent weeks, with tomato prices rising over 400% to record highs and households toiling under rising rates of everything from milk to cereals and spices, according to official data. Khetarpal said it was "re-engineered" by cutting price - and tomatoes - from its earlier cheapest offering of 59 rupees.įranchisee Jubilant said in May it witnessed a cheese price surge of 40% during 2022-23, and a 30% rise in chicken and paper boxes. The budget products are indeed being accompanied by a digital and physical marketing blitz across the nation - with stores, and even a posh New Delhi mall, plastered with banners, according to Reuters visits to stores across four Indian states.ĭomino's flagship inflation-buster is the 49-rupee pizza, which was launched in February. He said the meals would bring in more customers and boost sales and margins. They'll be the focus of promotion efforts in coming weeks, according to Akshay Jatia, executive director at Westlife Foodworld (WEST.NS), which runs 357 outlets in western and southern India. McDonald's (MCD.N) launched half-price meals in June. Merrill Pereyra, managing director of Pizza Hut in the Indian subcontinent, said the chain was developing products that "make the brand relevant and easy to access" for price conscious consumers in India, adding its budget pizzas were a hit with young people. Pizza Hut is aggressively promoting pizzas starting at 79 rupees ($0.96) that it launched last year and its India franchisee, Sapphire Foods (SAPI.NS), said it was the brand's lowest-priced globally. The hope is that low-price offers will draw people to stores and apps who might order more add-ons or upgrade, the executives said. CUSTOMERS EMPTY POCKETSĭomino's is not alone in zeroing in on prices in India, a highly price-sensitive market that is currently facing higher inflation than many other markets including the U.S. ![]() ![]() Pizza Hut also offers two medium pizzas for $5.99 each, but how does that compare to its special $7.Jubilant - whose Domino's business accounted for most of its $635 million in revenues last year - also aims to secure rent rebates from some store landlords by offering upfront payments, Khetarpal said, declining to give further details about cost benefits. The bigger pizza at Domino’s has a lower cost per square inch when you compare a regular-priced large pizza for $12.49 to a regular-priced medium for $9.99.īut its long-running special of two medium two-topping pizzas for $5.99 each changes everything. Read on to find out which pizza place offers the best bite for your buck… Domino’s Team Clark compared prices for 12-inch medium and 14-inch large pizzas at three national chains: Domino’s, Pizza Hut and Papa John’s. Think a bigger pizza is always a better value?īefore you place your next delivery order, check out this handy calculator we found that reveals the cost per square inch - this tool could save you some serious dough! The Best Pizza Value at Domino’s, Pizza Hut and Papa John’s ![]() getting sold 3 -5 duplicate or similar products, products with slight variations in the services provided and or names and many of them overlapping, and many of them duplicating free products that came with my pc. Apparently, over the years when intentionally renewing my Avast product, I was I. ![]() Further investigation revealed so much deceptive business practices that I feel it is intentional. When I investigated I was told that I had canceled a different Avast product. I proceeded to cancel my Avast product prior to that date, was shocked to find I had still been charged. Initially, I received a courtesy notice that a product would be renewed on the such and such date. The bottom line is that this is a company that has virtually no customer service and appears to be a dishonest racket. So for $42.79 I didn't even get their premium software but some useless side-app. ![]() In addition to that, it turned out that I do not have the premium version of their software but have some additional software that's supposed to just clean-up unnecessary files on my computer. My computer is only four-months old!!! There's not a thing wrong with it. He was going to refer me to a technician in my area to have my computer serviced. Instead he started rooting around in my browser history and telling me that I'd visited all these unsecured websites that had messed up my computer. I went ahead and allowed the guy to access my computer in order to activate the premium version of their software.īut that's not what the guy did. Whenever I call they want to have remote access to my computer. Again I got an Indian man at a call center. If I didn't get a refund then I should still have the premium version of the software, right? After four-months without a refund I called Avast back to verify that I should be entitled to the premium version of the software since I never got a refund. In addition to that the software kept prompting me to sign-up for the premium version. Still waitingĪfter 20-minutes on the phone I was told that my premium account had been canceled and the $42.79 charge would be refunded to my bank account. This problem began after my first use of the Avast boot scan. I'm still waiting, as my videos won't start, and when they finally do start they immediately start freezing. I made it very clear that e-mail is the only way I can be contacted. It's 15 June 2018 and I still haven't received an e-mail. ![]() Update on : I used the contact information Avast gave me in response to my complaint on this site to let them know my issues on 11 June 2018. I have the setting on for this, but it still keeps shutting off. Also, I'm continually having to cut the VPN on, and I want it on AT ALL TIMES. So, in a nutshell, my computer is locking and freezing in all websites and videos due to running their boot scan for the first time, I can't contact customer service because these unprofessionals don't have an international phone number on their website? And lastly, NO CHAT ROOM FOR TECH?!!! What the devil? For minimal customer service, I'll need someone from Avast (preferable a tech) to contact me with their E-MAIL ADDRESS so that I can contact them and perhaps get the problem resolved completely. What's more, it WinX DVD Ripper Platinum 7.5. ![]() The latest DVD may have 99 titles and the file size is larger than. 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